Publication Date
1981
Document Type
Dissertation/Thesis
First Advisor
Preston, Richard S.
Degree Name
M.S. (Master of Science)
Legacy Department
Department of Physics
LCSH
Mössbauer spectroscopy; Greenalite; Hornblende
Abstract
⁵⁷Fe Mössbauer spectra have been recorded at room temperature and liquid nitrogen temperature for greenalite from Gyr greenstone belts of Yilgran Block, Western Australia and two hornblendes from the Sierra Nevada Batholith, California. Measurements at more than one temperature are found to provide information of value in isolating the separate components of the complex spectra for these minerals and categorizing these iron ions according to charge (Fe²⁺ , Fe³⁺) and spin (high, low) state. The greenalite spectra have been resolved into three doublets due to Fe²⁺ ions. The quadrupole splittings of all three doublets in greenalite spectra are strongly dependent on temperature which indicates that the Fe²⁺ ions are in the high-spin state. The spectra of hornblende sample H9A have been resolved into four doublets due to Fe²⁺ ions in M₁, M₃, M₄ sites and two doublets due to Fe³⁺ ions. The spectra of hornblende sample G55C have been resolved into three doublets due to Fe²⁺ ions in M₁, M₃, M₄ sites and two doublets due to Fe³⁺ ions. The large temperature dependence of quadrupole splittings of Fe²⁺ doublets and the small temperature-independent quadrupole splittings of the Fe³⁺ doublets are indicative of the high-spin state of iron ions.
Recommended Citation
Noor, Harun Mohd, "Mössbauer study of two hornblendes and greenalite" (1981). Graduate Research Theses & Dissertations. 4017.
https://huskiecommons.lib.niu.edu/allgraduate-thesesdissertations/4017
Extent
30 pages
Language
eng
Publisher
Northern Illinois University
Rights Statement
In Copyright
Rights Statement 2
NIU theses are protected by copyright. They may be viewed from Huskie Commons for any purpose, but reproduction or distribution in any format is prohibited without the written permission of the authors.
Media Type
Text
Comments
Includes bibliographical references.||Includes illustrations.