Alt Title

Characterization of fluorine containing stationary phases by linear solvation energy relationships

Publication Date

2000

Document Type

Dissertation/Thesis

Degree Name

M.S. (Master of Science)

Legacy Department

Department of Chemistry

LCSH

Fluorine; Stationary phase (Chromatography); Solvation; Gas chromatography

Abstract

Linear solvation energy relationships (LSER) have been used successfully in the characterization of GC stationary phases and other materials. The LSER model has also been used to quantify solubility properties of the solute and solvent, by directly correlating the retention of a given solute on a particular stationary phase to intrinsic properties, such as the thermodynamic partition coefficient K. ... Recent work in our group has focused on correlating specific solubility properties of the solvent with molecular/structural features. Such studies are called quantitative structure-solubility relationships (QSSR). In a continuing effort to develop these quantitative structure-solubility relationships, this work aimed at characterizing three fluorinated phases for the purpose of expanding the current LSER data base, and also to examine effects of fluorine on solubility properties.

Comments

Includes bibliographical references (pages [43]-44)

Extent

44 pages

Language

eng

Publisher

Northern Illinois University

Rights Statement

In Copyright

Rights Statement 2

NIU theses are protected by copyright. They may be viewed from Huskie Commons for any purpose, but reproduction or distribution in any format is prohibited without the written permission of the authors.

Media Type

Text

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