Publication Date

1984

Document Type

Dissertation/Thesis

First Advisor

Bridges, Alexander J.

Degree Name

M.S. (Master of Science)

Department

Department of Chemistry

LCSH

Organosulphur compounds||Amines||Phenyl compounds

Abstract

By examining the reaction of 2-phenylsulfinylbuta-2,3-diene-1-yl acetate and 2-phenylsulfinylbut-1-en-3-yne with a series of amines, it was demonstrated that the enyne is not an intermediate in the reaction of the allenyl acetate with unhindered secondary amines. The preparation of a new butadiene, 2-acetoxy-3-phenylsulfinyl-1,3-butadiene from 2-phenylsulfinylbut-1-en-3-yne is described. The enyne reacts thermally with cyclopentadiene to give an E/Z mixture of 2-(Bicyclo-[2,2,l]-hept-6-en-2-ylidene)-2-phenylthio-ethanal in the absence of hindered amines and the norbornene, E,Z-2-(Bicyclo-[2,2,1]-hept-6-en-2-ylidene)-ethanal, in the presence of such amines.

Extent

viii, 62 pages

Language

eng

Publisher

Northern Illinois University

Rights Statement

In Copyright

Rights Statement 2

NIU theses are protected by copyright. They may be viewed from Huskie Commons for any purpose, but reproduction or distribution in any format is prohibited without the written permission of the authors.

Media Type

Text

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