Author

Wentong Tian

Publication Date

1994

Document Type

Dissertation/Thesis

First Advisor

Ballantine, David Stephen

Degree Name

M.S. (Master of Science)

Department

Department of Chemistry

LCSH

Gas chromatography||Solvation||Stationary phase (Chromatography)

Abstract

Linear solvation energy relationship (LSER) was used for characterization three stationary phases with cyano- function group : sebaconitrile, benzyl cyanide and tetracyanoethylated pentaerythritol(TCEPE). We examined the partition/retention behaviors of a thirty solute set on the above stationary phases at 120 °C with gas chromatography. With applying multiple linear correlation regression on the retention results, the characteristic coefficients of these phases are determined. For high volatile phase, such as, benzyl cyanide, we also explored an alternative approach to determine the characteristic coefficients at high temperature based on the retention behaviors at lower temperature. As judged by the regression criteria R2 and the residuals analyses, the LSER correlation coefficients obtained are of statistical validity. They provide a very good prediction for the solvation ability for the solute on the given stationary phase. Our study represent an effort to extend the LSER data base in terms of functional group representation, which is eventually a more effective approach to characterize the stationary phases of chromatography.

Comments

Includes bibliographical references (pages [66]-68)

Extent

vii, 68 pages

Language

eng

Publisher

Northern Illinois University

Rights Statement

In Copyright

Rights Statement 2

NIU theses are protected by copyright. They may be viewed from Huskie Commons for any purpose, but reproduction or distribution in any format is prohibited without the written permission of the authors.

Media Type

Text

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